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The Influence of Cement Composition on Superplasticizers’ Efficiency
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International Journal of Engineering (IJE)
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Volume:  3    Issue:  6
Pages:  521-670
Publication Date:   January 2010
ISSN (Online): 1985-2312
Pages 
577 - 587
Author(s)  
Ghada Bassioni - United Arab Emirates
 
Published Date   
31-01-2010 
Publisher 
CSC Journals, Kuala Lumpur, Malaysia
ADDITIONAL INFORMATION
Keywords   Abstract   References   Cited by   Related Articles   Collaborative Colleague
 
KEYWORDS:   cement, superplasticizers, adsorption 
 
 
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Fundamental interactions between polymeric superplasticizers and cement were studied. Cements with different alite-, belite-, C3A- and C4AF-contents were used. The use of commercially available superplasticizers like melamine formaldehyde sulfite- (MFS) and â-naphthalene sulfonic acid formaldehyde-(NSF) resins was investigated. These superplasticizers (industrial products) were characterized with the help of their molecular weights and polymeric radii, as well as by estimation of the anionic charge density in water and in the cement filtrate of four CEM I cements. Application data of the eight cement-superplasticizer-combinations (heat flow calorimetry and mini-slump tests) were obtained and the surface chemistry of the superplasticizers with cement (zeta potentials and superplasticizer adsorption on cement) was studied. 
 
 
 
1 a) S. Suzu, E. Okada and K. Hattori, “Adsorption of superplasticizers on cement” CAJ Review, 108-110, 1981. b) S. Goyal, M. Kumar, B. Bhattacharjee, “Effect of relative proportion of pozzolana on compressive strength of concrete under different curing conditions”, Int. J. Eng., 2(1): 20-34, 2008.
2 E. Asakura, H. Yoshida and H. Nakae, “Influence of superplasticizers on fluidity of fresh cement paste with different clinker phase composition”, In Proceedings of 9th Int. Cong. Chemistry of Cement, New Delhi, India, 5: 570-576, 1992.
3 K. Yamada, S. Ogawa and S. Hanehara, “Working Mechanism of Poly-Beta-Naphthalene Sulfonate and Polycarboxylate Superplasticizer Types from Point of Cement Paste Characteristics”, In Proceedings of. 6th CANMET/ACI Int. Conf. on Superplasticizers, Nice, France, 195: 367-382, 2000.
4 a) E. Sakai, J. K. Yamada and A. Ohta, “Molcular Structure and Dispersion-Adsorption Mechansims of Coomb-Type Superplasticizers used in Japan”, J. Adv. Concr. Tech. 1(1): 16-25, 2003. b) P. P. Bansal, M. Kumar, S. K. Kaushik “Effect Of Wire Mesh Orientation On Strength Of Beams Retrofitted Using Ferrocement Jackets”, Int. J. Eng. 2(1): 8-19, 2008.
5 G. Bassioni, “Global warming and Construction Aspects”, In Proceeding of the 7th International Scientific and Practical Conference on Environmental Technology Resources, Rezekne, Latvia, 2: 78-86, 2009.
6 G. Bassioni, J. Plank, “Untersuchungen zur kompetitiven Adsorption anorganischer Anionen am Modellsystem Kalksteinmehl”, GDCh Monographie, 36: 225-232, 2006.
7 J. Plank, G. Bassioni, Z. Dai, H. Keller, B. Sachsenhauser, N. Zouaoui, “Neues zur Wechselwirkung zwischen Zementen und Polycarboxylat-Fließmitteln”, ibausil-Tagungsband, 16: 579-598, 2006.
8 a) J. Plank, Ch. Hirsch, "Superplasticizer Adsorption on Synthetic Ettringite", In Proceedings of 7th CANMET/ACI Conference on Superplasticizers in Concrete, Berlin, Germany, 217: 283-298, 2003. b) A. Elazhary, Hassan Soliman, “Analytical Investigation of the Flow Hydrodynamics in Micro-Channels at High Zeta Potentials”, Int. J. Eng., 3(3): 267-279, 2008.
9 J. Plank, G. Bassioni, “Adsorption of Carboxylate on CaCO3 surface”, Z. Naturforsch. B, 62b: 1277-1284, 2007.
 
 
 
1 G. Bassioni, “A study towards “greener” construction”, Applied Energy, Volume 93, pp. 132–137, May. 2012.
2 S. B. Cui and F. W. He, “Study of Applied Properties of Aminosulphonic Acid Based Superplasticizer”, Applied Mechanics and Materials, Advances in Mechanical Engineering, Vols 52 – 54, pp. 1650-1655, Mar. 2011.
3 G. Bassioni and M. M. Ali, “Studying the physico-chemical properties of commercially available oil-well cement additives using calorimetry”, Journal of Thermal Analysis and Calorimetry, Feb. 2012.
 
 
 
1 docin
 
2 The Petroleum Institute, Abu Dhabi , United Arab Emirates
 
 
 
Ghada Bassioni : Colleagues  
 
 
 
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