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Controlled Method for Preparation and Characterization of Nanostructured Carbon Based Fe, Co -Containing Catalysts
Mai M. Khalaf, H.C.Ibrahimov, E.H.Ismailov, Y.H.YUSIFOV, N.M.ALIEVA
Pages - 1 - 11     |    Revised - 15-09-2012     |    Published - 25-10-2012
Volume - 2   Issue - 1    |    Publication Date - October 2012  Table of Contents
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KEYWORDS
Namoelectronics, Nanotechnology, Nanotubes
ABSTRACT
The iron, cobalt- carbon materials were synthesized as catalytic complex CTC and CTC modified chlorides of Fe (III), and Co (II) with controlled method. These catalytic complexes based on the reaction of aluminum and ethylene dichloride in liquid paraffin, and due to its composition and structure in comparison with the Friedel-Crafts catalysts, has a higher stable catalytic activity. The obtained xerogel (designated as CTC-110) was submitted to thermal treatment at 200, 400, 600, and 850 ◦C. and the resulting materials were characterized by means of different techniques, such as X-ray fluorescence microscopy (XRFM), thermal analyses (TG/DSC), X-ray diffractometer (XRD), and Dynamic light scattering analyses for particle size determination of the targeted samples. As a result, studies have shown that under given conditions the reaction of Al with dichloroethane leads to the improvement the carbon matrix, then after modifying this catalytic complex with different metal chloride (iron and cobalt) at different calcined temperatures leads also to modification in physical and chemical properties of the formed catalytic complexes and the different techniques which we used confirmed these results. Key word: Nanostructured materials, CTC, Fe/CTC, Co/CTC
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Dr. Mai M. Khalaf
Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan - Azerbaijan
mai_kha1@yahoo.com
Professor H.C.Ibrahimov
Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan - Azerbaijan
Professor E.H.Ismailov
Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan - Azerbaijan
Mr. Y.H.YUSIFOV
National Academy of Sciences - Azerbaijan
Mr. N.M.ALIEVA
National Academy of Sciences - Azerbaijan