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The Influence of Cement Composition on Superplasticizers’ Efficiency
Ghada Bassioni
Pages - 577 - 587 | Revised - 30-12-2009 | Published - 31-01-2010
Published in International Journal of Engineering (IJE)
MORE INFORMATION
KEYWORDS
cement, superplasticizers, adsorption
ABSTRACT
Fundamental interactions between polymeric superplasticizers and cement were studied. Cements with different alite-, belite-, C3A- and C4AF-contents were used. The use of commercially available superplasticizers like melamine formaldehyde sulfite- (MFS) and â-naphthalene sulfonic acid formaldehyde-(NSF) resins was investigated. These superplasticizers (industrial products) were characterized with the help of their molecular weights and polymeric radii, as well as by estimation of the anionic charge density in water and in the cement filtrate of four CEM I cements. Application data of the eight cement-superplasticizer-combinations (heat flow calorimetry and mini-slump tests) were obtained and the surface chemistry of the superplasticizers with cement (zeta potentials and superplasticizer adsorption on cement) was studied.
| 1 | Vickers, L., van Riessen, A., & Rickard, W. D. (2015). Fire-Resistant Geopolymers: Role of Fibres and Fillers to Enhance Thermal Properties. Springer. |
| 2 | Didouche, Z. (2014). Effet du dosage et du type de superplastifiant sur le comportement calorimétrique des ciments composés (Doctoral dissertation). |
| 3 | Bassioni, G., & Ali, M. M. (2013). Studying the physico-chemical properties of commercially available oil-well cement additives using calorimetry. Journal of thermal analysis and calorimetry, 111(1), 295-303. |
| 4 | Coelho, S. A. G. B. P. (2012). Estudo das propriedades dos adjuvantes na compatibilidade/robustez cimento/adjuvante. |
| 5 | Kheribet, R., Samar, M., Benmounah, A., Safi, B., & Said, M. (2012). Effects of alkaline and alkaline-earth ions on the rheological behavior and zetametric study of two cement pastes (artificial cement portland-CEMI and cement resistant to the sulfates-CRS) with the polynaphthalene sulfonate (PNS). |
| 6 | Bassioni, G. (2012). A study towards “greener” construction. Applied Energy, 93, 132-137. |
| 7 | G. Bassioni and M. M. Ali, “Studying the physico-chemical properties of commercially available oil-well cement additives using calorimetry”, Journal of Thermal Analysis and Calorimetry, Feb. 2012. |
| 8 | G. Bassioni, “A study towards “greener” construction”, Applied Energy, Volume 93, pp. 132–137, May. 2012. |
| 9 | S. B. Cui and F. W. He, “Study of Applied Properties of Aminosulphonic Acid Based Superplasticizer”, Applied Mechanics and Materials, Advances in Mechanical Engineering, Vols 52 – 54, pp. 1650-1655, Mar. 2011. |
| 10 | Cui, S. B., & He, F. W. (2011, April). Study of applied properties of aminosulphonic acid based superplasticizer. In Applied Mechanics and Materials (Vol. 52, pp. 1650-1655). |
| 11 | Bassioni, G., Pillay, A. E., El Kadi, M., Fegali, F., Cheong Fok, S., & Stephen, S. (2010). Tracking traces of transition metals present in concrete mixtures by inductively-coupled plasma mass spectrometry studies. European Journal of Mass Spectrometry, 16(6), 679. |
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| G. Bassioni, “Global warming and Construction Aspects”, In Proceeding of the 7th International Scientific and Practical Conference on Environmental Technology Resources, Rezekne, Latvia, 2: 78-86, 2009. | |
| G. Bassioni, J. Plank, “Untersuchungen zur kompetitiven Adsorption anorganischer Anionen am Modellsystem Kalksteinmehl”, GDCh Monographie, 36: 225-232, 2006. | |
| J. Plank, G. Bassioni, “Adsorption of Carboxylate on CaCO3 surface”, Z. Naturforsch. B, 62b: 1277-1284, 2007. | |
| J. Plank, G. Bassioni, Z. Dai, H. Keller, B. Sachsenhauser, N. Zouaoui, “Neues zur Wechselwirkung zwischen Zementen und Polycarboxylat-Fließmitteln”, ibausil-Tagungsband, 16: 579-598, 2006. | |
| K. Yamada, S. Ogawa and S. Hanehara, “Working Mechanism of Poly-Beta-Naphthalene Sulfonate and Polycarboxylate Superplasticizer Types from Point of Cement Paste Characteristics”, In Proceedings of. 6th CANMET/ACI Int. Conf. on Superplasticizers, Nice, France, 195: 367-382, 2000. | |
Associate Professor Ghada Bassioni
- United Arab Emirates
gbassioni@pi.ac.ae
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